They were pictured painting the town red at exclusive member's club Annabel's once lockdown restrictions were easy over the weekend to allow bars to open.
And following their night out, Rod Stewart and his wife Penny Lancaster hopped on a plane to enjoy a getaway to Dubrovnik, Croatia, on Tuesday.
The rocker, 75, looked typically dapper in his holiday attire as he sported an open-neck white linen shirt, which he teamed with a pair of pale grey shorts.
Rod didn't hold back on his accessories, as he donned a baker boy style cap and paid homage to his football club with a diamond-encrusted Celtic necklace.
The singer finished his look with a pair of knitted Adidas trainers and an arty Dolce and Gabanna satchel bag, which was covered in colourful sketches.
Penny, 49, ensured she captured Rod's fabulous look as she got out her phone to take pictures of the Maggie May hitmaker.
Meanwhile, Penny herself looked seriously chic in a pretty white lace blouse, which she teamed with a pair of thigh-grazing denim mini shorts.
The model added a fierce edge to her ensemble with a pair of leopard print ballet pumps and a matching shopper bag, which she slung over her shoulder.
Penny displayed her endless pins in the chic ensemble, while shielding her eyes from the rays with a pair of stylish reflective shades.
Rod and Penny : Night On The Town
Annabel's club London on July 04, 2020
Dynamic duo: Rod Stewart, 75, and wife Penny Lancaster, 49, led a slew of stars getting dressed up to head out on Saturday, as bars, pubs and restaurants across the nation reopened
But his model wife stole the show in a striking fuchsia satin midi dress, which boasted tie-wrap detailing around the waist, finishing the look with a pair of black pointed-toe heels and an understated clutch bag.
The couple walked out of the exclusive celebrity hot-spot hand in hand as they headed home after their night out.